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@Helsa: not sure if you just mean that you've run Math a lot, but just in case, the Hellhound skull is a drop from the end chest, not from Hellhounds themselves. I played Math Adv with 3 players a few days back and got a hellhound skull so it's possible. It used to require a 3-player run, and while it is probably true that you can now acquire one on a solo run, why not appease the goddesses and run with 3 just to increase your odds?
Regarding leather drops, I have been Rank 1 Ingredient Hunting for a long time and I am not seeing any noticeable increase in leather drops. Maybe Ingredient Hunting has ranked a few times and are starting to notice the benefits?